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Step 02 Lithography

Spin Coater

Laurell Technologies Corporation, North Wales, PA, USA

HIGH ● Every lithography step begins with spin-coating

Role in QLT Fabrication

The spin coater applies thin, uniform films of photoresist and functional polymers to the foundry-returned SiN chips. Three distinct spin-coat jobs:

JobMaterialTarget ThicknessSpeedDurationPurpose
B1/G4 ResistSPR-220-3.0 (positive)3.0 μm ± 0.1 μm3000 RPM30 sPhotolithography masking
B4 PVDF-TrFE70/30 copolymer in MEK500 nm ± 50 nm4000 RPM60 sPiezoelectric Poovey switch layer
Optional ARCARC coating100–200 nm5000 RPM30 sLithography uniformity

Process Criticality

Resist thickness uniformity directly determines:

  • Exposure dose consistency ● ±10% thickness variation causes ±10% dose variation
  • Pattern resolution ● thicker resist limits minimum feature size
  • Etch mask integrity ● insufficient resist thickness leads to mask erosion during RIE
  • PVDF-TrFE film quality ● Poovey switch performance depends on uniform piezoelectric layer

Edge Bead Consideration

Spin coating on small die (5×5 mm or 10×10 mm) produces significant edge beads ● thick resist ridges at substrate edges. For QLT:

  • Edge bead width: ~0.5–1.0 mm from edge (acceptable; our features are > 1 mm from edge)
  • Edge bead removal (EBR): Not required for current designs but available via solvent dispensed at edge during spin
  • Fragment adapter chuck ensures small die are centered and level during coating

Recommended Configuration

The WS-650 series is the most widely used research spin coater worldwide, with thousands installed in university and startup cleanrooms.

ParameterSpecification
ManufacturerLaurell Technologies Corporation, North Wales, PA, USA
ModelWS-650-23B (standard research-grade, 650 series)
Max substrate150 mm (6") wafer; 5" × 5" (127 mm) square
Speed range0–12,000 RPM (programmable; based on 100 mm Si wafer)
Acceleration0–29,000 RPM/s
ControlDigital microprocessor; 20+ stored recipes; PC interface (object-oriented software)
Bowl materialProprietary NPP co-polymer (acid/base/solvent resistant); PTFE Hostaflon® TFM-1600 optional
ChuckVacuum chuck standard; fragment adapters for pieces as small as 3 mm
LidWater-clear ECTFE or PVC domed lid; interlocked (rotation disabled when open)
Bowl designClosed clamshell with internal gutter; eliminates splash-back; no splash rings needed
Exhaust/DrainAdjustable down-flow exhaust and drain (standard on EDC™ models); controller monitors exhaust pressure
Motor sealProprietary labyrinth seal; N₂-purged; particle-free on sub-micron level
SafetyDoor interlock; latch; rotation lock until lid closed and 0 RPM sensed
Power300 W; universal input 95–240 VAC, 47/63 Hz
N₂/CDA60–70 PSIG for labyrinth seal purge (3 ft³/hr standard motor; 20 ft³/hr high-performance)
Vacuum25–28 inHg; 4.5 SCFM at 0 inHg
Footprint~35 cm × 35 cm × 25 cm (compact benchtop)
Weight~15 kg (33 lbs)
ParameterSpecification
ManufacturerLaurell Technologies Corporation, North Wales, PA, USA
ModelWS-650-23B (standard research-grade, 650 series)
Max substrate150 mm (6") wafer; 5" × 5" (127 mm) square
Speed range0–12,000 RPM (programmable; based on 100 mm Si wafer)
Acceleration0–29,000 RPM/s
ControlDigital microprocessor; 20+ stored recipes; PC interface (object-oriented software)
Bowl materialProprietary NPP co-polymer (acid/base/solvent resistant); PTFE Hostaflon® TFM-1600 optional
ChuckVacuum chuck standard; fragment adapters for pieces as small as 3 mm
LidWater-clear ECTFE or PVC domed lid; interlocked (rotation disabled when open)
Bowl designClosed clamshell with internal gutter; eliminates splash-back; no splash rings needed
Exhaust/DrainAdjustable down-flow exhaust and drain (standard on EDC™ models); controller monitors exhaust pressure
Motor sealProprietary labyrinth seal; N₂-purged; particle-free on sub-micron level
SafetyDoor interlock; latch; rotation lock until lid closed and 0 RPM sensed
Power300 W; universal input 95–240 VAC, 47/63 Hz
N₂/CDA60–70 PSIG for labyrinth seal purge (3 ft³/hr standard motor; 20 ft³/hr high-performance)
Vacuum25–28 inHg; 4.5 SCFM at 0 inHg
Footprint~35 cm × 35 cm × 25 cm (compact benchtop)
Weight~15 kg (33 lbs)
OptionDescriptionCost Impact
PTFE HousingHostaflon® TFM-1600 / Teflon® AF; for high-temp chemistry + sub-micron particle work+$2,000–$3,000
FEP Teflon® LinersRemovable, reusable chamber liners; included on HL series+$200–$400
High-Performance DriveUp to 12,000 RPM (substrate/chuck dependent)+$500–$1,000
Fragment AdapterVacuum adapter for substrates as small as 3 mm+$200–$400
On-Deck Mounting (OND)Earthquake-proof base; remote controller; for glovebox or wet-bench mounting+$500–$1,000
Teflon® Control ValvesDrip-free UD-3 injectors; convert between pump, pressure vessel, or syringe dispensing+$200–$500
Dispense Pump (BP-1)Inexpensive, disposable dispense pump+$100
Bowl-Wash RoutineAutomated bowl wash + dry cycle programmable into recipesIncluded in firmware
AlternativeProsConsApprox. Price (New)
Laurell WS-400BLower cost; 4" max; simplerSmaller wafer limit; fewer features$4,000–$6,000
SÜSS MicroTec Delta 80Production-grade; integrated hot plate; auto dispenseExpensive; overkill$30,000–$50,000
Headway Research PWM32Classic lab workhorse; provenOlder design; fewer automation features$3,000–$5,000 used
SCS G3P-8Excellent for thick resistsLess common$5,000–$8,000 used
Ossila Spin CoaterUltra-compact; affordableSmall substrate only (25 mm); not cleanroom grade$3,000 new
Chinese generic (MTI, SETCAS)Very low costPoor repeatability; no US support$500–$2,000

Process Integration

Pre-Coat Preparation

  • Verify substrate cleanliness (acetone → IPA → DI rinse → N₂ dry on wet bench #06)
  • Dehydration bake: 200°C hot plate, 5 min (removes surface moisture for resist adhesion)
  • Optional HMDS vapor prime (improves resist adhesion on SiO₂ surface)
  • Cool substrate to room temperature (1–2 min on cleanroom bench)

Coating Sequence

  • Place substrate on spin coater chuck under yellow safelight
  • Verify vacuum hold
  • Dispense SPR-220-3.0: 2–3 mL static puddle on center
  • Close lid
  • Run programmed recipe (Step 1 → 2 → 3 as above)
  • Open lid; remove with tweezers
  • Transfer to soft-bake hot plate (115°C, 90 s)

Post-Coat Inspection

  • Visual inspection: uniform color (thin-film interference); no comets, streaks, or particles
  • Optional: measure thickness with reflectometer or profilometer
  • Target: 3.0 μm ± 0.1 μm across center 80% of substrate
  • Edge bead: acceptable if < 1 mm width from edge

Bowl Maintenance (After Each Session)

  • Run bowl-wash program: spin IPA or acetone at 500 RPM to clean internal surfaces
  • Wipe bowl interior with cleanroom wipe + IPA
  • Replace aluminum foil liner if used
  • Verify drain is clear; no dried resist buildup

Vendor Options & Pricing

New System Cost

ConfigurationEstimated New Price
WS-650-23B (standard, NPP co-polymer bowl, vacuum chuck set)$7,000–$10,000
WS-650-23B with PTFE Hostaflon® housing + PC interface$9,000–$13,000
WS-650-23B + fragment chuck adapter + FEP liner$8,000–$11,000
WS-400B (4" max, basic)$4,000–$6,000

Laurell does not publish prices. Obtain quote at laurell.com/quote.php.

Used/Refurbished Market

ConditionWS-650WS-400Headway PWM32
"As-is"$2,000–$4,000$1,500–$3,000$1,000–$2,500
Tested / functional$4,000–$6,000$2,500–$4,000$2,000–$3,500
Refurbished w/ warranty$6,000–$8,000$4,000–$5,500$3,000–$5,000

Where to Buy

DealerWebsiteNotes
Laurell Technologies (OEM)laurell.comNew units; custom configs; US-made; 2–4 week delivery
eBayebay.comFrequent WS-650 listings; $2k–$5k used
LabXlabx.comLab equipment marketplace
DOTmeddotmed.comOccasionally lists spin coaters
University surplusVariousCheck nearby university surplus stores

Cost History

SPIN COATER PRICE TREND (Laurell WS-650):

New: ~$7-10k consistently for 10+ years (very stable pricing)
Used: $2-6k depending on condition (abundant supply)

TREND: Extremely stable market. Spin coaters are COMMODITY items.
New purchase from Laurell recommended due to low cost,
full warranty, and exact configuration control.

Our Budget Recommendation

Buy NEW: $8,000 (Laurell WS-650-23B)

  • Justification: New cost is low enough that used savings ($2–4k) don't justify contamination or worn bearing risk
  • Include: Standard NPP co-polymer bowl, vacuum chuck set for 100 mm wafers + fragment adapter (3 mm minimum), FEP Teflon® liner, PC interface software
  • Lead time: 2–4 weeks from Laurell (stock item)

Facility Requirements

Floor Space

DimensionRequirement
Footprint35 cm × 35 cm (14" × 14") ● benchtop unit
With workspace0.8 m × 0.6 m section of cleanroom bench
Weight15 kg (33 lbs)
No floor reinforcement needed

Electrical

ParameterRequirement
SupplyAny standard outlet: 120 V or 240 V, single-phase (universal 95–240 V input)
CircuitStandard 15 A outlet
Power300 W peak; ~5 W idle
No special electrical requirements✅ Plug and play

Utilities

UtilitySpecification
Vacuum25–28 inHg; dedicated pump or house line (diaphragm pump: $200–$500)
N₂ / CDA60–70 PSIG; clean, dry; 3–20 ft³/hr consumption
ExhaustFume hood or downdraft recommended (resist solvents: PGMEA; MEK for PVDF-TrFE)
Exhaust flow100–200 CFM local exhaust

Vibration / Sound / Lighting

ParameterSpecification
Vibration sensitivityNONE ● generates vibration, doesn't receive it
CautionDon't place directly adjacent to mask aligner
Noise50–60 dB(A) during spin (moderate whine)
Special lightingYES ● YELLOW SAFELIGHT if dispensing photoresist
Co-locationSame yellow-lit zone as mask aligner is ideal

Safety & Handling

HazardRisk LevelControl
MEK fume exposure (PVDF-TrFE coating)MediumSpin under fume hood or downdraft; MEK flash point: -9°C (flammable)
Resist solvent vapors (PGMEA)LowGeneral ventilation; PGMEA is low toxicity
Rotating chuckLowLid interlock prevents access during spin
Chemical splashLowClosed lid design contains all fluid

PPE

  • Safety glasses
  • Nitrile gloves
  • Lab coat
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