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Step 02 Lithography

DUV Stepper/Scanner

Canon FPA-3000 / Nikon NSR-S205D CRITICAL ● Primary production lithography for all photonic features ≥180nm CD

Role in QLT Fabrication

The DUV (Deep Ultraviolet) stepper/scanner is the primary pattern-definition tool for QLT's photonic integrated circuits. Using a 248 nm KrF excimer laser source, it transfers photomask patterns onto photoresist-coated wafers with sub-200 nm resolution and < 50 nm overlay accuracy. Every waveguide, directional coupler, MZI arm, grating coupler, alignment mark, and dummy fill structure on the chip is defined by this tool.

At 248 nm wavelength, the theoretical resolution limit is governed by the Rayleigh criterion: R = k₁ × λ / NA, where k₁ is the process factor (0.4–0.8), λ = 248 nm, and NA is the numerical aperture (0.5–0.68 for dry KrF). This yields minimum feature sizes of 150–400 nm — well within the requirements for all QLT photonic structures where the smallest critical dimension is ~180 nm (waveguide width).

  • Waveguide patterning ● Defines 800 nm × 350 nm Si₃N₄ waveguide cores with < 1 nm sidewall roughness (after RIE optimization)
  • Grating couplers ● Periodic structures with 600–700 nm pitch, requiring ~300 nm line/space resolution
  • MZI mesh routing ● Defines all 28 MZI arms, 32 phase shifter windows, and waveguide crossings for the 8-mode Clements mesh
  • Alignment marks ● Multi-layer overlay marks for subsequent heater, metal, and cladding-open lithography steps
  • OPC spiral waveguides ● Archimedean spirals (2–8 cm total length, 20 µm pitch) with Euler-curve transitions
  • Poovey switch windows ● Defines trench openings (34 µm × 20 µm) for oxide undercut and switch release

Lithography Technology Comparison

TechnologyWavelengthResolutionThroughputCostQLT Use
KrF DUV (our primary)248 nm150–250 nm60–120 WPH$8–12M newAll production layers
ArF DUV193 nm65–130 nm100–150 WPH$15–30M newFoundry (LIGENTEC) only
ArF immersion193 nm (H₂O)38–65 nm150–250 WPH$30–60M newNot needed
i-line stepper365 nm350–500 nm40–80 WPH$0.5–2M usedNon-critical layers only
Contact/proximity365–405 nm1–3 µm10–30 WPH$50–200KPrototype only
E-beam direct-writeElectron< 10 nm0.1–1 WPH$3–5MODR patterning + masks

Photoresist and Process Requirements

ParameterTargetToleranceMeasurement
Resist typeChemically amplified DUV resist (e.g., TOK THMR-iP3650, JSR KrF M78Y)
Resist thickness500–800 nm± 10 nmEllipsometry / reflectometry
BARC (bottom anti-reflection)60–90 nm (tuned to 248 nm)± 3 nmEllipsometry
Exposure dose20–50 mJ/cm²± 2%Dose monitor / test exposures
Focus control± 0.15 µm± 0.3 µm DOFLeveling sensor (air gauge or optical)
CD uniformity< 5 nm 3σ (isolated lines)< 10 nmCD-SEM
Overlay accuracy< 30 nm (layer-to-layer)< 50 nmOverlay metrology (KLA Archer)

Technical Specifications

ParameterCanon FPA-3000 EX5Nikon NSR-S205D
Wavelength248 nm (KrF excimer)248 nm (KrF excimer)
Numerical aperture0.600.68
Resolution180 nm (isolated) / 200 nm (dense)150 nm (isolated) / 180 nm (dense)
Field size22 mm × 22 mm26 mm × 33 mm
Reduction ratio
Overlay accuracy≤ 35 nm (matched machine)≤ 25 nm (matched machine)
Wafer sizeUp to 200 mmUp to 200 mm
Throughput60–80 WPH80–120 WPH
AlignmentFIA (field image alignment)EGA + FIA dual-alignment
AutofocusAir-gauge leveling sensorMulti-point AF sensor
Reticle stageSingle reticle, automatic loadingSingle reticle, automatic cassette
Laser sourceKrF excimer (Cymer ELS-6610)KrF excimer (Cymer/Gigaphoton)
ParameterASML PAS 5500/300
Wavelength248 nm (KrF)
Numerical aperture0.63
Resolution180 nm
Field size22 mm × 22 mm
Overlay≤ 30 nm
Throughput60–80 WPH
AvailabilityUsed market (widely available, strong service ecosystem)

Process Integration

QLT PROCESS FLOW ● DUV Stepper (Step B3):

PRE-REQUISITES:
├── Si₃N₄ film deposited and annealed (Steps B1–B2)
├── Wafer cleaned (solvent clean + O₂ plasma descum)
├── Photomask set fabricated:
│   ├── Mask 1: Waveguide core (WG_FULL etch)
│   ├── Mask 2: Shallow etch (WG_SHALLOW, if applicable)
│   ├── Mask 3: Cladding window opening (CLAD_OPEN)
│   ├── Mask 4: Heater/metal pattern (METAL)
│   └── Mask 5: Contact pad opening (PAD_OPEN)
└── Masks: 6" × 6" × 0.25" quartz, Cr pattern, pellicle-protected

STEP 1: Resist Coating (Track System)
├── HMDS vapor prime: 150°C, 60 s (promotes resist adhesion)
├── Spin BARC: 60 nm, 3000 RPM, 30 s → bake 175°C, 60 s
├── Spin DUV resist: 600 nm, 2500 RPM, 30 s
├── Soft bake: 110°C, 90 s (removes solvent)
└── Edge bead removal: 2 mm from wafer edge

STEP 2: Alignment & Exposure
├── Load wafer onto stepper chuck (vacuum)
├── Global alignment: EGA using alignment marks from prior layer
│   └── First layer: use wafer notch/flat for coarse alignment
├── Per-field fine alignment: FIA on die marks
├── Expose: 30 mJ/cm² (dose optimized per focus-exposure matrix)
├── Step-and-repeat across wafer (field size matches die layout)
├── Typical: 20–100 fields per 150/200 mm wafer
└── Total exposure time: ~30–60 s per wafer

STEP 3: Post-Exposure Bake (PEB) & Develop
├── PEB: 115°C, 60 s (activates acid catalyst in resist)
├── Develop: 0.26N TMAH (tetramethylammonium hydroxide), 60 s puddle
├── Rinse: DI water, 30 s
├── Post-develop inspection: optical microscope + CD-SEM sampling
└── Rework possible: strip resist and re-coat if defects found

STEP 4: Pattern Transfer (Etch)
├── RIE (reactive ion etch) of Si₃N₄ using CHF₃/O₂/Ar plasma
├── Etch rate: ~50 nm/min in Si₃N₄
├── Selectivity to SiO₂: ~2:1 (BOX acts as etch stop)
├── Target: vertical sidewalls (90° ± 1°), RMS roughness < 1 nm
├── Endpoint: optical emission spectroscopy (OES)
└── Over-etch: 10–15% into BOX for margin

STEP 5: Resist Strip & Clean
├── O₂ plasma ash: 300 W, 2 min (removes bulk resist)
├── Wet strip: hot NMP or EKC-265 (removes residues)
├── DI water rinse → spin dry
└── Inspection: verify clean wafer, no resist residues

PROCESS REPEATS FOR EACH MASK LAYER (typically 3–5 litho passes)

Vendor Options & Pricing

New System Pricing

ModelManufacturerSubstratePrice (2025–2026)Lead Time
Canon FPA-3000 EX5Canon (Japan)Up to 200 mm$8,000,000–$12,000,00024–36 weeks
Nikon NSR-S205DNikon (Japan)Up to 200 mm$10,000,000–$15,000,00024–40 weeks
ASML PAS 5500/300ASML (Netherlands)Up to 200 mm$8,000,000–$12,000,000 (new discontinued; refurb only)N/A (used market)

Refurbished / Used Market

ModelConditionPriceLead TimeSource
Canon FPA-3000 EX3/EX5Refurbished (laser refurb incl.)$1,500,000–$3,500,0008–16 weeksClassOne, SurplusGlobal
Nikon NSR-S204D / S205DRefurbished to factory spec$2,000,000–$4,000,00010–20 weeksNikon refurb program, TEL
ASML PAS 5500/250Refurbished$800,000–$2,000,0006–14 weeksASML refurb, SurplusGlobal
ASML PAS 5500/300Tested / Refurbished$1,500,000–$3,000,0008–16 weeksSurplusGlobal, FabSurplus
Canon FPA-3000 i5+ (i-line, backup)Refurbished$200,000–$600,0004–8 weeksClassOne, Used-Line

Photomask Costs

Mask TypeFeature SizeCost per MaskLead TimeNotes
KrF 5× / 4× reticle (Cr on quartz)≥ 180 nm$5,000–$15,0002–4 weeksStandard mask shops (Photronics, Toppan)
KrF with OPC (optical proximity correction)150–180 nm$15,000–$40,0003–6 weeksRequires OPC simulation + verification
Phase-shift mask (AttPSM)< 150 nm$30,000–$80,0004–8 weeksRarely needed for photonics
Full mask set (5 layers)$25,000–$75,0003–6 weeksOne-time NRE cost

Facility Requirements

DUV STEPPER FACILITY REQUIREMENTS:

SPACE:
├── Footprint: 4 m × 6 m (stepper) + 3 m × 6 m (resist track)
├── Height: ≥ 3.5 m (for optics column and crane access)
├── Weight: 8,000–15,000 kg (requires reinforced floor, ≤ 200 kg/m²)
├── Vibration: CRITICAL ● VC-D or better (≤ 6.25 µm/s RMS, 1–80 Hz)
│   └── Requires vibration-isolated concrete pedestal or air-spring mounts
└── Adjacent: resist coating track, develop station, CD-SEM

POWER:
├── 3-phase, 208/480V, 80–150A
├── Total consumption: 30–60 kW (stepper) + 10–20 kW (track)
├── UPS recommended for controller and alignment system
└── Clean power (voltage regulation ± 2%)

ENVIRONMENTAL:
├── Temperature: 22.0 ± 0.1°C (CRITICAL — lens performance)
├── Humidity: 45 ± 3% RH
├── Cleanroom: ISO 3–4 (Class 10–100) within the litho bay
│   └── Higher class than rest of fab
├── Air handling: laminar flow, ULPA-filtered, ≥ 0.3 m/s down-flow
└── Pressure: positive relative to adjacent areas

UTILITIES:
├── Cooling water: 10–25 kW chilled water (20 ± 0.5°C)
├── Compressed dry air: 6 bar, dew point < -40°C
├── N₂: high purity for purge and pneumatics
├── Vacuum: roughing pump for wafer chuck
└── Exhaust: solvent exhaust for resist track (HMDS, PGMEA, NMP)

EXCIMER LASER:
├── KrF gas: pre-mix (Kr/F₂/Ne), $500–$1,000/fill
├── Gas lifetime: 50–100 million pulses per fill
├── Laser maintenance: window replacement every 1–2 billion pulses
├── Annual laser service contract: $100,000–$300,000
└── F₂ gas: TOXIC + CORROSIVE ● requires dedicated gas cabinet

Safety & Handling

Hazard Summary

HazardSourceRisk LevelControls
UV radiation (248 nm)KrF excimer laserCRITICALFully enclosed light path; interlock on all access panels; UV-blocking windows
F₂ gas leakExcimer laser gas supplyHIGHGas cabinet with scrubber; F₂ monitor (TLV 1 ppm); auto-shutoff
Chemical exposure (resists)PGMEA, NMP, TMAH developerMEDIUMSolvent exhaust; PPE (goggles, gloves); SDS on file
Ozone generationUV interaction with ambient O₂MEDIUMN₂ purge in beam path; ozone monitor in laser enclosure
Electrical (high voltage)Excimer laser power supply (20–40 kV)HIGHLocked panels; capacitor discharge interlock; LOTO procedures
Heavy equipment8–15 ton stepper, lens columnMEDIUMOverhead crane for installation; seismic anchoring

Laser Safety

EXCIMER LASER SAFETY (Class 4 laser system):

1. NEVER look into the beam path — 248 nm UV causes instant corneal burns
2. All access panels are interlocked — opening any panel shuts off laser
3. Laser enclosure windows are UV-absorbing (block 248 nm completely)
4. Wear UV-blocking safety glasses (OD ≥ 5 at 248 nm) during maintenance
5. F₂ gas is HIGHLY TOXIC and CORROSIVE:
   ├── TLV-TWA: 1 ppm, IDLH: 25 ppm
   ├── Gas cabinet with dedicated scrubber is MANDATORY
   ├── F₂ monitor must be interlocked to laser gas supply valve
   └── Leak test all connections before and after gas fill
6. Ozone is generated in un-purged beam paths — monitor at ceiling level
7. Laser service: only by trained laser engineer with LOTO lockout
8. Annual laser safety audit per ANSI Z136.1
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